Carbon nanotubes are excellent candidates for the development of
nano-reinforced polymer composite materials. However, assurance of
homogeneous dispersion, interfacial compatibility between the carbon
nanotube and the polymer, and exfoliation of the aggregates of carbon
nanotubes, are required for the successful integration of carbon
nanotubes into nanocomposites. The present study is focused primarily
upon the electrical and mechanical properties of catalytically-grown
multi-walled carbon nanotube-reinforced epoxy composite materials.
Particular emphasis is placed upon the effect of carbon loading on the
electrical conductivity and the influence of temperature on the loss
factor and modulus for the composite materials. The results indicate
that the electrical properties of the composite would not be changed
from those of the bulk polymer until the average distance between the
carbon nanotubes is reduced such that either electron tunneling through
the polymer or physical contacts may be formed. Among the challenges
introduced in the fabrication of carbon nanotube-filled polymer
composites is the necessity to creatively control and make use of
surface interactions between carbon nanotubes and polymeric chains in
order to obtain an adequate dispersion throughout the matrix without
destroying the integrity of the carbon nanotubes. Frequency domain
material properties are therefore limited to applications where strains
are small and stress is approximately linear with strain and the strain
rate. Frequency domain material properties become irrelevant if the
material exhibits nonlinear elastic behavior or is subjected to large
strains. Depending on the type of polymers in the matrix, above a
certain temperature limit, degradation starts or cross-linking starts.
The deformed elastic body possess an amount of potential energy equal to
the initial amount of potential energy minus the amount of energy
irreversibly dissipated. The modulus and loss factor variables of a
damping material are highly dependent upon the temperature of the
damping material and the vibration frequency. Because of their
viscoelastic nature, the stress and strain in viscoelastic materials are
not in phase, and, in fact, exhibit hysteresis. The resonant frequency
is related to the modulus of the catalytically-grown multi-walled carbon
nanotube-reinforced epoxy composite.
Keywords: Composite materials; Electrical properties;
Mechanical properties; Carbon nanotubes; Electrical conductivity; Loss
modulus