The rate of the chemical reaction Xe+Xe++e-between 4200-7600°K has been followed by microwave absorption in a shock tube. Results are explained in terms of the mechanism : M+XezM+Xe*+M+Xe++e-.The complex rates are resolved into two empirical rate constants, kl and k2. From the observed activation energies it is concluded that b g c , and in this case the empirical kl is a and the empirical k:! is c. The activation energies are : El = 8-4& 1 eV, and E2 = 3.7fl eV (the ionization potential of xenon is 12.1 eV), and the cross-section for the second process is about 103 times that for the first. By virtue of imprisonment of resonance radiation, the quantum of energy represented by Xe* is held in the system for a large number of collisions.