We use the one-dimensional object-oriented particle-in-cell Monte Carlo collision code oopd1 to explore the charged particle densities, the electronegativity, the electron energy probability function (EEPF), and the electron heating mechanism in a single frequency capacitively coupled oxygen discharge when the applied voltage amplitude is varied. We explore discharges operated at 10 mTorr, where electron heating within the plasma bulk (the electronegative core) dominates, and at 50 mTorr where sheath heating dominates. At 10 mTorr the discharge is operated in combined drift-ambipolar (DA) and α-mode and at 50 mTorr it is operated in pure α-mode. At 10 mTorr the effective electron temperature is high and increases with increased driving voltage amplitude, while at 50 mTorr the effective electron temperature is much lower, in particular within the electronegative core, where it is roughly 0.2 -0.3 eV, and varies only a little with the voltage amplitude.