1980
DOI: 10.1002/pssa.2210620238
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Electron microscopic studies of ferroelectric and ferroelastic Gd2(MoO4)3. IV. Polarization Reversal and Field Induced Phase Transformation

Abstract: A technique of in‐situ application of an electric field to specimen crystals in an electron microscope is developed. By using this technique the polarization reversal process in Gd2(MoO4)3 is studied at various temperatures. It is found that the side wise motion of the domain walls is dominant in the polarization reversal process at room temperature, and the nucleation process of reversed domains at the antiphase boundaries is important at higher temperatures. The field induced phase transformation is also stu… Show more

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Cited by 20 publications
(9 citation statements)
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“…However, sample charging, local heating, and beam damage can cause problems. As a result, only a relatively small number of in situ experiments on domain wall motion under applied lateral bias or ferroelectric phase transition by optical microscopy, 165,166 scanning, 167,168 and transmission [169][170][171][172][173][174][175] electron microscopy have been reported.…”
Section: (2) Polarization and Domain Dynamics In Ferroelectric Materialsmentioning
confidence: 99%
“…However, sample charging, local heating, and beam damage can cause problems. As a result, only a relatively small number of in situ experiments on domain wall motion under applied lateral bias or ferroelectric phase transition by optical microscopy, 165,166 scanning, 167,168 and transmission [169][170][171][172][173][174][175] electron microscopy have been reported.…”
Section: (2) Polarization and Domain Dynamics In Ferroelectric Materialsmentioning
confidence: 99%
“…In some of the early works, domain switching in ferroelectrics has been investigated by applying an electric field parallel to the electron beam in the TEM. [8][9][10] More recently, Tan et al have developed an alternative in situ TEM technique by applying an electric field perpendicular to the electron beam on the sample surface. [11][12][13][14][15] These studies mainly focused on the electric-field-induced microcracking and intersection of domains in Pb͑Mg 1/3 Nb 2/3 ͒O 3 -PbTiO 3 single crystals and PbZr x Ti 1−x O 3 ceramics.…”
mentioning
confidence: 99%
“…In contrast, the atomic resolution afforded by contemporary aberration-corrected transmission electron microscopy (TEM) is ideal for characterizing crystalline defects and following the ferroelectric switching process in situ. There are, however, only a handful of TEM studies of ferroelectric domain switching in bulk crystals [14][15][16] . The direct characterization of ferroelectric switching in thin-film heterostructures is now possible with the recent integration of scanning probe and TEM 17,18 .…”
mentioning
confidence: 99%