1993
DOI: 10.1002/kin.550250507
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Electron‐transfer kinetics and activation barriers for the reductions of nitrosonium and nitronium ions in aprotic solvents

Abstract: Using the cyclic voltammetry (CV), the electron-transfer kinetics for the reductions of NO+ and NOz' cations have been studied at the Pt electrode in nitromethane, sulfolane, and propylene carbonate. The heterogeneous rate constants have been determined by two independent procedures from the transfer coefficient a, the diffusion coefficient D, from a detailed examination of the CV-peak separations, and from an inspection of the values of the cathodic peak potentials at different scan rates. The results have be… Show more

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Cited by 6 publications
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