1988
DOI: 10.1021/ic00279a013
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Electron-transfer reactions of technetium and rhenium complexes. 2. Relative self-exchange rate of the M(I)/M(II) couples [M(DMPE)3]+/2+ where M = Tc or Re and DMPE = 1,2-bis(dimethylphosphino)ethane

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Cited by 21 publications
(23 citation statements)
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“…where M = Re or Tc and An = Np or Pu were calculated from the appropriate half-reactions [3,6] and are presented in Table 1.…”
Section: Resultsmentioning
confidence: 99%
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“…where M = Re or Tc and An = Np or Pu were calculated from the appropriate half-reactions [3,6] and are presented in Table 1.…”
Section: Resultsmentioning
confidence: 99%
“…Triply recrystallized samples of [Re'iDMPE^lFaCSOj and [TC^DMPE^FSCSOB were used to prepare stock solutions of Tc(I) and Re(I) by weight. The synthesis and characterization by Xray techniques of [Re^DMPE^FjCSOa and [Tc^DMPE^FCSOa have been previously reported [3]. The ionic strength of the An(VI), Tc(I) and Re(I) solutions was maintained at 0.3 M with appropriate amounts of NaCl and Na 2 C0 3 .…”
Section: Methodsmentioning
confidence: 99%
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“…[4] Thus, fewer than 50 articles comprise the entire literature of Re(ii) chemistry and these can be further reduced to 15 fundamental reports. [5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20] The rhenium chemistry of this oxidation state is dominated by phosphorus ligands. A few notable exceptions are complexes of binding ligands such aromatic amines or isocyanides.…”
Section: Introductionmentioning
confidence: 99%
“…[19,[25][26][27][28] Here a brief diversion is here needed for a broader perspective. About 20 years ago, the molecular cluster [Mn 12 O 12 (CH 3 CO 2 ) 16 (H 2 O) 4 ] was discovered to exhibit slow magnetic relaxation at low temperatures. [29][30][31] This unusual behavior is attributed to the presence of a high-spin ground state of S = 10 combined with an axial magnetic anisotropy of D = -0.5 cm -1 .…”
Section: Introductionmentioning
confidence: 99%