The origin of electron traps, which induce leakage currents in SiO, films, is predicted to be an oxygen (0) vacancy from first-principles total-energy calculations. Once a neutral 0 vacancy traps holes, it spontaneously changes to a large distorted structure [l]. The distorted 0 vacancy can capture electrons, and remains as an electron trap in SiO, films. These results give a microscopic explanation for a trap model that is empirically deduced from experiments [2]. The energy level of the generated electron 'trap exists near the band offset between the conduction band of SiO, and that of Si. From these results, the electron trap originating from a hole trapped 0 vacancy can be considered as one of origins of the so-called stress-induced leakage currents in SiO, films.