Electronic and bonding properties of mixed-ligand copper(II) complexes of N-(2-picolyl)picolinamide (pmpa). X-ray crystal structures of [Cu(pmpa) (4-methylimidazole)(H2O)](H2O)(ClO4) and [Cu(pmpa)(4-methylpyridine)(H2O)] (H2O)(ClO4)

Novel seven-coordinate complexes formulated as [CuL(BH 4 ) 2 ], [CuL(BH 4 )(NO 2 )] and [CuL(NO 2 ) 2 ] (L = 1,4,7triazacyclononane) have been prepared and structurally characterized by elemental analyses, spectroscopic data (u.v., i.r. and e.p.r.), magnetic susceptibility and conductivity measurements. The results reveal that the complexes are non-electrolytic. The coordination geometry around the copper(II) ion is a seven coordinated square pyramidal structure with three nitrogen atoms of the 1,4,7-triazacyclononane and either four hydrogen atoms of two bidentate tetrahydroborate groups or two hydrogen atoms of the bidentate tetrahydroborate group and two oxygen atoms of the bidentate nitrite group or four oxygen atoms of two bidentate nitrito groups. A cyclic voltammetric study on the complexes indicates an irreversible redox couple (Cu II /Cu I ) in DMF, giving a voltage of ca. À0.37 V versus s.c.e.

show abstract

Coordination chemistry with pyridine/pyrazine amide ligands. Some noteworthy results

Rajput

Mukherjee

2013

Coordination Chemistry Reviews

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Electronic and bonding properties of mixed-ligand copper(II) complexes of N-(2-picolyl)picolinamide (pmpa). X-ray crystal structures of [Cu(pmpa) (4-methylimidazole)(H2O)](H2O)(ClO4) and [Cu(pmpa)(4-methylpyridine)(H2O)] (H2O)(ClO4)

Cited by 21 publications

References 15 publications

Dinuclear Copper(II) Complexes of Two Homologous Pyrazine‐Based Bis(terdentate) Diamide Ligands

Dinuclear Copper(II) Complexes of Two Homologous Pyrazine‐Based Bis(terdentate) Diamide Ligands

Bidentate bonding mode of tetrahydroborate and nitrite towards copper(II) in open-faced macrocyclic complexes

Coordination chemistry with pyridine/pyrazine amide ligands. Some noteworthy results

Contact Info

Product

Resources

About