1976
DOI: 10.1103/physrevb.14.3744
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Electronic configuration of samarium sulphide and related compounds: Mössbauer-effect measurements and a model

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Cited by 88 publications
(19 citation statements)
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“…As seen from Fig. 1(a), ν estimated from high-T experiments shows a continuous evolution with P [10][11][12]. A similar smooth P -variation is observed in the conductivity σ measured at T = 150 K [ Fig.…”
Section: +supporting
confidence: 57%
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“…As seen from Fig. 1(a), ν estimated from high-T experiments shows a continuous evolution with P [10][11][12]. A similar smooth P -variation is observed in the conductivity σ measured at T = 150 K [ Fig.…”
Section: +supporting
confidence: 57%
“…Continuous pressure evolution of (a) mean valence ν at high temperature [10][11][12] and (b) conductivity ratio σ(P )/σ(P = 0.6 GPa) at 150 K. For the definition of ν, see text. (c) P -T phase diagram of golden SmS.…”
Section: +mentioning
confidence: 99%
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“…The theoretically calculated samarium valency was found to be equal to 2.55+ and 2.86+ for high and low spin solutions, respectively. The experimentally estimated one is about 2.6+ using spectroscopic methods and susceptibility measurements [66][67][68] and about 2.8+ using the Vegards-low analysis of lattice constant measurements [68].…”
Section: High Pressure Golden Phase Of Smsmentioning
confidence: 99%
“…In materials such as the samarium chalcogenides as well as in many cerium intermetallic compounds, the valence fluctuates rapidly between f n and f n−1 but the average valence is nevertheless homogeneous [3,4]. Driven by hybridization with itinerant carriers, this behavior is intimately related to the Kondo effect [5].…”
mentioning
confidence: 99%