The chalcogenide glass is known to exhibit a variety of vector photo‐deformations. The present work studies the deformation in glassy As‐S(Se) films and flakes, which are laid on viscous grease layers. Upon bandgap illumination of linearly polarized cw laser light, the film and flake exhibit anisotropic wrinkles and extensions, respectively, while the directions change with the composition. As2S(Se)3 samples deform in the direction orthogonal to the electric field of the light, but pure Se deforms in parallel to the electric field. And, in the As‐Se system, an orthogonal‐parallel directional change appears at the As content of ∼1 at.%. X‐ray diffraction and Raman‐scattering spectroscopy detect no anisotropic atomic changes. The orthogonal deformation has been ascribed to optical pressure, while the parallel in Se may be triggered by polariton‐plasmon waves. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)