Electronic Properties of Bi-Sn Diluted Alloys

Fedotov, A. S.; Свито, И. А.; Гусакова, С. В.; Shepelevich, V. G.; Saad, A.; Mazanik, A.V.

doi:10.1016/j.matpr.2015.05.088

Cited by 3 publications

(2 citation statements)

References 10 publications

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“…Similar effects have been reported whereby the presence of Bi in dendritic Bi–Cu alloys promotes formate production as compared to CO evolution observed on Cu–In alloys . Alloying can also enhance the electrical conductivity of electrodes as observed for PbO 2 that had been alloyed with Bi and/or Sn. − It has also been demonstrated that CuSn alloys can promote CO 2 RR in the presence of [BMIM] + -based ionic liquids under nonaqueous conditions …”

Section: Introductionsupporting

confidence: 66%

Selective CO₂ Reduction over Rose’s Metal in the Presence of an Imidazolium Ionic Liquid Electrolyte

Kunene

Atifi

Rosenthal

2019

ACS Appl. Energy Mater.

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The electrochemical reduction of CO 2 into reduced carbon compounds is a compelling strategy to sustainably synthesize fuels and commodity chemicals using renewable energy sources. Although promising post-transition metal electrocatalysts have been developed from monometallic thin films, limited effort has been dedicated to the use of trimetallic alloys for CO 2 electrocatalysis. In this work, we have explored the electrocatalytic effect of alloying Sn, Pb, and Bi, which are all reported as being individually active catalysts for CO 2 reduction to different extents. It is demonstrated that the well-known soldering alloy Bi 50 Sn 22 Pb 28 (Rose's metal = RM) promotes the conversion of CO 2 to CO in MeCN electrolyte containing millimolar concentrations of the ionic liquid additive [BMIM]OTf. Planar RM electrocatalysts evolve CO with Faradaic efficiencies as high as 95% with average geometric current densities of j tot = 3−10 mA/cm 2 . XPS analysis shows evidence for the accumulation of metal oxides on the RM surface following CO 2 electrocatalysis, which may influence the activity of the alloy.

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Section: Introductionsupporting

confidence: 66%

Selective CO₂ Reduction over Rose’s Metal in the Presence of an Imidazolium Ionic Liquid Electrolyte

Kunene

Atifi

Rosenthal

2019

ACS Appl. Energy Mater.

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“…The cooling rate K achieved in our experiments was estimated following the relation used by Fedotov et al [52] for experiments performed under static conditions:…”

Section: Melt-spinning Processmentioning

confidence: 99%

Structural and Electrical Properties Characterization of Sb1.52Bi0.48Te3.0 Melt-Spun Ribbons

et al. 2017

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Melt-spinning (MS) has been reported as a promising tool to tailor the microstructure of bulk thermoelectric materials leading to enhanced thermoelectric performances. Here, we report on a detailed characterization of p-type Bi 0.48 Sb 1.52 Te 3 ribbons produced by melt-spinning. The microstructure of the melt-spun ribbons has been studied by means of X-ray diffraction, scanning and transmission electron microscopy (TEM). The analyses indicate that the ribbons are highly-textured with a very good chemical homogeneity. TEM reveals clear differences in the microstructure at large and short-range scales between the surface that was in contact with the copper wheel and the free surface. These analyses further evidence the absence of amorphous regions in the melt-spun ribbons and the precipitation of elemental Te at the grain boundaries. Low-temperature electrical resistivity and thermopower measurements (20-300 K) carried out on several randomly-selected ribbons confirm the excellent reproducibility of the MS process. However, the comparison of the transport properties of the ribbons with those of bulk polycrystalline samples of the same initial composition shows that MS leads to a more pronounced metallic character. This difference is likely tied to changes in deviations from stoichiometry due to the out-of-equilibrium conditions imposed by MS.

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Effect of nano-phased bismuth–tin alloy surface coating on tribo-mechanical properties of basalt fiber reinforced composites

Dhand

Han²,

Kim³

et al. 2022

Journal of Materials Research and Technology

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Electronic Properties of Bi-Sn Diluted Alloys

Cited by 3 publications

References 10 publications

Selective CO₂ Reduction over Rose’s Metal in the Presence of an Imidazolium Ionic Liquid Electrolyte

Selective CO₂ Reduction over Rose’s Metal in the Presence of an Imidazolium Ionic Liquid Electrolyte

Structural and Electrical Properties Characterization of Sb1.52Bi0.48Te3.0 Melt-Spun Ribbons

Effect of nano-phased bismuth–tin alloy surface coating on tribo-mechanical properties of basalt fiber reinforced composites

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Electronic Properties of Bi-Sn Diluted Alloys

Cited by 3 publications

References 10 publications

Selective CO2 Reduction over Rose’s Metal in the Presence of an Imidazolium Ionic Liquid Electrolyte

Selective CO2 Reduction over Rose’s Metal in the Presence of an Imidazolium Ionic Liquid Electrolyte

Structural and Electrical Properties Characterization of Sb1.52Bi0.48Te3.0 Melt-Spun Ribbons

Effect of nano-phased bismuth–tin alloy surface coating on tribo-mechanical properties of basalt fiber reinforced composites

Contact Info

Product

Resources

About

Selective CO₂ Reduction over Rose’s Metal in the Presence of an Imidazolium Ionic Liquid Electrolyte

Selective CO₂ Reduction over Rose’s Metal in the Presence of an Imidazolium Ionic Liquid Electrolyte