We
investigate the flow and mixing characteristics for an electroosmotic
flow through a wavy micromixer using surface charge heterogeneity.
The Laplace equation for the external electric field, Poisson–Boltzmann
equation for potential distribution, and continuity and momentum equations
for fluid flow and species transport equation have been solved by
imposing the appropriate boundary conditions using a finite element
method-based numerical solver. The results are presented by varying
the phase lag of sinusoidal zeta potential between the two walls (Δϕ),
Debye parameter (κ), geometrical wave number (n), dimensionless wall amplitude (α), and diffusive Peclet
number (Pe). The results reveal that the phase lag
has a strong confluence on the flow field and mixing performance together
with other physicochemical parameters. The strength of primary flow
as well as the size of the recirculation zones increases with Δϕ
and κ, and additional recirculation zones are formed in the
core of the mixer for Δϕ = 0. The value of mixing efficiency
is close to 100% up to a critical value of Pe (Pe
Cri), the value of which is greater for the
nonuniformly charged surface potential with a nonzero phase lag. For
thinner EDL (κ = 150), a fully mixed state based on 90% mixing
is achieved up to higher values of Pe with a higher
flow rate at Δϕ = π/2 and π. Also, for Δϕ
= π/2, the mixing efficiency as well as the flow rate enhances
with the amplitude of the channel walls for Pe
Cri ≤ Pe ≤323.5. Moreover, for
Δϕ = 0, the value of mixing efficiency increases with
α for 786 ≤ Pe ≤1000 with a 9.17%
decrement in the flow rate for the change in α from 0.05 to
0.25.