Electroreduction of carbon dioxide to multi-electron reduction products using poly(ionic liquid)-based Cu-Pd catalyst

Li, Xiaoqiang; Duan, Guo‐Yi; Yang, Xian-Xia; Han, Lijun; Xu, Bo

doi:10.1016/j.fmre.2021.12.009

Cited by 13 publications

(6 citation statements)

References 49 publications

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“…In comparison to the recently published electromethanation of CO 2 (Figure a), Cu–DCD 40 demonstrates high selectivity (FE) and activity (partial current density) of electromethanation. ,− To evaluate the stability of the as-prepared catalyst, “pause electrolysis” to suppress the carbonate issue is adopted in this work . The pause electrolysis is shown in Figure b.…”

Section: Resultsmentioning

confidence: 98%

Efficient Electromethanation from CO₂ on Monodisperse Cu-Based Catalysts

Sun

et al. 2023

Energy Fuels

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The electrochemical CO 2 reduction reaction (CO 2 RR) is a promising approach to upgrading CO 2 into methane (CH 4 ) and other high-value-added chemicals, critical for lowering carbon emissions and mitigating the greenhouse effect. However, the selectivity of CO 2 RR to methane remains low at the current densities required for commercialization. Herein, we report a simple one-step synthesis of monodisperse copper-based catalysts for efficient electromethanation of CO 2 . Through rational regulation of active sites, the selectivity for methane production can reach as high as 57.02% under the current density of 300 mA cm −2 as a result of suppressed C−C coupling for improved *CO hydrogenation. This work offers an effective strategy to regulate Cu-based catalysts to manage the hydrogenation of *CO for CO 2 RR toward CH 4 formation.

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Section: Resultsmentioning

confidence: 98%

Efficient Electromethanation from CO₂ on Monodisperse Cu-Based Catalysts

Sun

et al. 2023

Energy Fuels

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“…Jackson D. Scholten received his Bachelor's degree in chemistry from UFRGS in 2005. He completed his Master's (2007) and Ph.D. (2011) degrees in Chemistry at UFRGS. Currently, he is an Assistant Professor at the Institute of Chemistry�Department of Inorganic Chemistry at UFRGS.…”

Section: Acknowledgmentsmentioning

confidence: 99%

“…The most promising systems reported so far involve Cu NPs@PILs of the type 13.1-X (Figure a and entries 16, 17, and 19, Table ). ,, The synergy between PIL 13.1 and Cu NPs enables CO 2 RR at relatively low applied potentials with high current densities, particularly when utilizing carbon paper or GDE and flow cells. Electrocatalysts based on Cu NPs, doped with ions adsorbed in the polymer layer (Cu(I) and Pd(II)) were prepared.…”

Section: Electrocatalysismentioning

confidence: 99%

“… ,, The synergy between PIL 13.1 and Cu NPs enables CO 2 RR at relatively low applied potentials with high current densities, particularly when utilizing carbon paper or GDE and flow cells. Electrocatalysts based on Cu NPs, doped with ions adsorbed in the polymer layer (Cu(I) and Pd(II)) were prepared. In all cases, the C 2 + FE exceeded 68% at current densities above 260 mA/cm 2 (geometric).…”

Section: Electrocatalysismentioning

confidence: 99%

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Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis

Dupont,

Leal,

Lozano

et al. 2024

Chem. Rev.

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“…Li et al 102 constructed a novel Cu–Pd catalyst Cu@PIL@Pd by impregnating PdCl2 into the Cu@PIL with Cl-as the anion. It was found that the Cu@PIL@Pd-2 catalyst exhibited the highest FE toward C 2+ of 68.7% with a high partial current density of 178.3 mA cm −2 at a cathodic potential of −1.01 V vs. RHE.…”

Section: Copper-based Bimetallic Materialsmentioning

confidence: 99%