2019
DOI: 10.1103/physreve.100.042616
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Electrorotation of semiconducting microspheres

Abstract: We study experimentally the electrorotation (ROT) of semiconducting microspheres. ZnO microspheres obtained by a hydrothermal synthesis method are dispersed in KCl aqueous solutions and subjected to rotating electric fields. Two ROT peaks are found in experiments: a counterfield peak and a cofield peak at somewhat higher frequencies. These observations are in accordance with recent theoretical predictions for semiconducting spheres. The counterfield rotation is originated by the charging of the electrical doub… Show more

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Cited by 12 publications
(13 citation statements)
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“…In fact, DEP and ICEP always tend to counterbalance one another, and gold spheres should keep stationary in DC limits from a theoretical perspective [42]. Nevertheless, dipolophoresis takes place in static fields in practical experiments; in that the present theory of ICEP would routinely overestimate the ICEO flow velocity by about one to two orders of magnitude, resulting in the dominating role of DEP over ICEP [43,44].…”
Section: Introductionmentioning
confidence: 87%
“…In fact, DEP and ICEP always tend to counterbalance one another, and gold spheres should keep stationary in DC limits from a theoretical perspective [42]. Nevertheless, dipolophoresis takes place in static fields in practical experiments; in that the present theory of ICEP would routinely overestimate the ICEO flow velocity by about one to two orders of magnitude, resulting in the dominating role of DEP over ICEP [43,44].…”
Section: Introductionmentioning
confidence: 87%
“…Considering semi-conducting particles, the same lowfrequency behavior can be observed. Then, particles show two dispersions [51,52]: A low-frequency dispersion from the EDL charging (according to Eq. (4)) and a high-frequency dispersion from the Maxwell-Wagner polarization (since σ P of semi-conducting particles is only around 0.1 S/m instead of 5 × 10 7 S/m as in the case of fully conductive particles).…”
Section: Polarization Of Metal and Semiconducting Particlesmentioning
confidence: 99%
“…In particular, manipulation of metal and semiconducting particles dispersed in aqueous electrolytes has received much attention in the last decade. Examples of particle manipulation by AC fields include the transport of metal spheres and nanowires [3,4], orientation of metal [5][6][7][8] and semiconducting nanowires [9][10][11], continuous rotation of metal spheres and nanowires [12][13][14][15][16][17], and self-assembly of metal nanowires [18,19]. Additionally, the electrical manipulation of metallo-dielectric Janus spheres has been recently investigated and electrokinetic phenomena such as transport [20,21], orientation [22], rotation [23], and assembly [24] of Janus spheres have been demonstrated.…”
Section: Introductionmentioning
confidence: 99%