2008
DOI: 10.1143/jpsj.77.123713
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Emergence of Antiferromagnetic Correlation in LiTi2-xVxO4 via 7Li NMR

Abstract: We report 7 Li NMR studies of V-substitution effects on the spinel oxide superconductor LiTi 2 O 4 (T c ¼ 13:4 K). In LiTi 2Àx V x O 4 (x ¼ 0 { 0:4), the V substitution for the Ti site suppressed the relative volume fraction of superconductivity faster than T c . From the observation of a fairly homogeneous increase in 7 Li nuclear spin-lattice relaxation rate, we conclude that the V substitution changes electron correlation effects through electron carrier doping from quarter electron filling 3d 0:5 to 3d 1:5… Show more

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Cited by 7 publications
(6 citation statements)
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“…Hence it can be said that anomalous quantum criticality is observed in Y-0.4 compound. Such features are not uncommon and have been reported in other compounds [30].…”
Section: Resultssupporting
confidence: 64%
“…Hence it can be said that anomalous quantum criticality is observed in Y-0.4 compound. Such features are not uncommon and have been reported in other compounds [30].…”
Section: Resultssupporting
confidence: 64%
“…short-range AFM ordering has been reported in V-doped LTO by nuclear magnetic resonance 11 and in LiV 2 O 4 by inelastic neutron scattering 46 . Note that the AMR measurements cannot be used to tell whether the AFM is static or dynamic.…”
Section: Discussionmentioning
confidence: 98%
“…4(c)], but we cannot tell whether it is Curie-Weiss-like or not due to the fact that it is difficult to cleanly separate a possible signal from the substrate. The emergence of short-range antiferromagnetic ordering has been reported in V-doped LTO by nuclear magnetic resonance (30) and in LiV 2 O 4 by inelastic neutron scattering (31). Perhaps, a new theoretical study is in order as to whether local spin scattering or fluctuations could result in a smooth change of the sign of the MR. Another possible explanation of the present MR behavior is grain boundary scattering.…”
Section: (B)mentioning
confidence: 96%
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“…T c and electrical properties of lithium titanate drastically changes with fluctuation of stoichiometry. It is reported in the literature, that maximum of superconducting transition temperature T c = 13 K is found for x close zero (0 6 x 6 0.1) [3][4][5]. Depending on x parameter, lithium titanate can exhibit metallic (x = 0) or insulating (x = 0.33) properties at room temperature [4,6,7].…”
Section: Introductionmentioning
confidence: 99%