Breakup temperatures in central collisions of 197 Au 1 197 Au at bombarding energies E͞A 50 to 200 MeV were determined with two methods. Isotope temperatures, deduced from double ratios of hydrogen, helium, and lithium isotopic yields, increase monotonically with bombarding energy from 5 to 12 MeV, in qualitative agreement with a scenario of chemical freeze-out after adiabatic expansion. Excited-state temperatures, derived from yield ratios of states in 4 He, 5,6 Li, and 8 Be, are about 5 MeV, independent of the projectile energy, and seem to reflect the internal temperature of fragments at their final separation from the system. [ S0031-9007(98) . The temperatures were derived from double ratios of helium and lithium isotopic yields while the excitation energies were obtained by adding up the kinetic energies of the product nuclei and the mass excess of the observed partition with respect to the ground state of the reconstructed spectator nucleus. The double-bended shape of the caloric curve and its similarity to predictions of microscopic statistical models [2][3][4], has stimulated considerable experimental and theoretical activities. In particular, the second rise of the temperature to values exceeding 10 MeV at high excitation energies has initiated the discussion of whether nuclear temperatures of this magnitude can be measured reliably (see , and references given in these recent papers) and whether this observation may indeed be linked to a transition towards the vapor phase [7,8]. Obviously, a well-founded understanding of the significance of the employed temperature observables [9] is indispensable when searching for signals of the predicted liquid-gas phase transition in nuclear matter.Here, we present the results of temperature measurements for central collisions of 197 Au 1 197 Au at incident energies E͞A 50 to 200 MeV. These collisions are characterized by a collective radial flow of light particles and fragments which, over the covered energy range, evolves as a dynamical phenomenon closely connected to the initial stages of the reaction [10]. Global equilibrium is clearly not achieved. If local equilibrium is reached, the associated temperatures should reflect the adiabatic cooling of the rapidly expanding system. Two temperature observables were used simultaneously. Isotope temperatures were deduced from double ratios of isotopic yields [11] and excited-state temperatures were derived from the correlated yields of lightparticle coincidences [9,12,13]. It will become evident from the diverging results that this represents more than a methodical test and that the two types of thermometers are sensitive to different stages of the fragment formation and emission.Beams of 197 Au with E͞A 50, 100, 150, and 200 MeV, provided by the heavy-ion synchrotron SIS, were directed onto targets of 75 mg͞cm 2 areal density. Two multidetector hodoscopes, consisting of 96 and of 64 Si-CsI(Tl) telescopes in closely packed geometries, were placed on opposite sides with respect to the beam axis. Four high-resolution te...