Shale gas resources have emerged as critical resources
in global
energy. Pakistan has a substantial unconventional shale gas potential.
However, shale gas in Pakistan, like in the United States and China,
is still poorly developed compared to other unconventional resources.
Shale reservoirs exhibit extremely poor permeability for production
by conventional means. Numerous approaches have been applied to extract
unconventional shale gas energy resources, including acid treatment
and hydraulic fracturing. However, due to copious concerns, many countries
have banned such practices. Hence, waterless fracturing techniques
have the potential to alleviate such issues. In such situations, cryogenic
fracturing by liquid nitrogen (LN2) is an imperative stimulation
option for tight formations. Hence, we obtained samples from the Sembar
shale formation of the lower Indus basin in Pakistan and experimentally
investigated the effects of pre- and post-treatment using LN2 under various time cycles (30, 60, and 90 min). The study provides
information about mineralogical, microstructural, and petro-physical
properties. Sembar shale samples were exposed to LN2 for
aging at various time cycles to generate fractures. The cryogenic
LN2 pre- and post-treatment effects were quantitatively
characterized using atomic force microscopy (for topography), scanning
electron microscopy (for microstructural properties), energy dispersive
spectroscopy (for elemental composition), petro-physical quantification
(for porosity and permeability), and nanoindentation (for rock-mechanical
properties). The results reveal that, before LN2 treatment,
Sembar exhibited nominal pore-throat sizes. However, the post-treatments
of cryogenic LN2 were very effective in creating microcracks
of up to 17 μm. Similarly, the petro-physical properties exhibited
a significant increase after LN2 treatment. The mean indentation
moduli decreased from 24.34 to 12.25 GPa for 50 mN force and 20.15
to 10.42 GPa for 200 mN force. The topographic study found increased
surface roughness from 356 to 778 nm due to the LN2 treatment
of 90 min. Cryogenic LN2 treatment can improve the pore
connectivity of shale samples and significantly enhance the flowing
capacity, which may greatly increase the productivity of unconventional
shale gas reservoirs.