Electrification of the transportation industry is necessary; however, range anxiety has proven to be a major hindrance to individuals adopting electric vehicles (EVs). Agrivoltaic systems (AVS) can facilitate the transition to EVs by powering EV charging stations along major rural roadways, increasing their density and mitigating range anxiety. Here we conduct case study analyses of future EV power needs for Oregon, USA, and identify 174 kha of AVS viable agricultural land outside urban boundaries that is south facing and does not have prohibitive attributes (designated wetland, forested land, or otherwise protected lands). 86% highway access points have sufficient available land to supply EV charging stations with AVS. These AVS installations would occupy less than 3% (5 kha) of the identified available land area. Installing EV charging stations at these 86% highway access points would yield 231 EV charging stations with a median range of 5.9 km (3.6 mi), a distance comparable to driver expectations, suggesting that this approach would serve to mitigate range anxiety. AVS powered rural charging stations in Oregon could support the equivalent of 673,915 electric vehicles yr−1, reducing carbon emissions due to vehicle use in OR by 3.1 mil MTCO2 yr−1, or 21%.