CO2 is widely used for enhanced oil recovery (EOR) as a result
of its high ability of washing oil and favorable injectivity, especially
for a tight oil reservoir. During the EOR process, the oil recovery
is significantly affected by gas channeling and the sweep efficiency
of CO2 is limited. Herein, we report CO2-switchable
smart wormlike micelles (WLMs) based on sodium dodecyl sulfate (SDS)
and diethylenetriamine (DETA) to prevent gas channeling of CO2 in a tight fractured oil reservoir. The proof to the microstructure,
formation mechanism, and plugging performance of CO2-switchable
WLMs was studied by cryo-transmission electron microscopy, dynamic
light scattering, nuclear magnetic resonance, rheology, and plugging
property measurement. The results indicated that the system can be
reversibly circulated between spherical micelles and wormlike micelles
by repeatedly bubbling and removing CO2. When CO2 is introduced to the solution, part of DETA molecules is protonated
and two SDS molecules are “bridged” to form a pseudo-gemini
surfactant by non-covalent electrostatic attraction, behaving as a
high-viscosity fluid. Upon removal of CO2, the protonated
DETA molecules return to the original state, causing the pseudo-gemini
structure to be destroyed and the viscosity of the fluid to be recovered.
Moreover, on the basis of the results of the plugging property measurement,
the solution presents conspicuous injection and plugging performance.
This WLM viscoelastic fluid might have potential application in the
enhancement of CO2 flooding in a tight fracture reservoir.