Glasses based on borophosphate with the formula 42.5P2O5 -42.5B2O3 -(15-x) Li2O -xMoO3 mol% where 𝑥 = (0 ≤ 𝑥 ≥ 15) were manufactured using the melt-quenching methodology.The status of prepared samples was identified by (XRD). The temperature of the glass transition Tg, the temperature of onset glass crystallisation Tc and the temperature of the crystallisation Tp were evaluated using a differential thermal analyser (DTA). The energy gap (𝐸 𝑜𝑝𝑡 ), Urbach (𝐸 𝑢 ), and parameters of dispersion were calculated through the data of optical spectra. Physical properties were determined and calculated, such as molar refractivity, metallization, electron polarizability, electronegativity, loss of reflection and dispersion parameters. Raising MoO3 at the expense of Li2O was used to assess the level of protection. For radiation protection applications, the glasses under investigation had superior characteristics.