Enhanced Switching Reliability of Hf_0.5Zr_0.5O₂ Ferroelectric Films Induced by Interface Engineering

Abstract

Ferroelectric materials have been widely researched for applications in memory and energy storage. Among these materials and benefiting from their excellent chemical compatibility with complementary metal−oxide−semiconductor (CMOS) devices, hafnia-based ferroelectric thin films hold great promise for highly scaled semiconductor memories, including nonvolatile ferroelectric capacitors and transistors. However, variation in the switched polarization of this material during field cycling and a limited understanding of the responsible mechanisms have impeded their implementation in technology. Here, we show that ferroelectric Hf 0.5 Zr 0.5 O 2 (HZO) capacitors that are nearly free of polarization "wake-up"�a gradual increase in switched polarization as a function of the number of switching cycles�can be achieved by introducing ultrathin HfO 2 buffer layers at the HZO/electrodes interface. High-resolution transmission electron microscopy (HRTEM) reveals crystallite sizes substantially greater than the film thickness for the buffer layer capacitors, indicating that the presence of the buffer layers influences the crystallization of the film (e.g., a lower ratio of nucleation rate to growth rate) during postdeposition annealing. This evidently promotes the formation of a polar orthorhombic (O) phase in the as-fabricated buffer layer samples. Synchrotron X-ray diffraction (XRD) reveals the conversion of the nonpolar tetragonal (T) phase to the polar orthorhombic (O) phase during electric field cycling in the control (no buffer) devices, consistent with the polarization wake-up observed for these capacitors. The extent of T−O transformation in the nonbuffer samples is directly dependent on the duration over which the field is applied. These results provide insight into the role of the HZO/ electrodes interface in the performance of hafnia-based ferroelectrics and the mechanisms driving the polarization wake-up effect.

Effect of ZnO Interfacial Seed Layer in Sol–Gel Grown ZnMgO Ferroelectric

“…To encourage the growth of the ferroelectric wurtzite phase in sol–gel synthesized ZnMgO, the addition of an interfacial seed layer of ZnO prior to ZnMgO deposition was studied. A similar approach using HfO 2 interfacial layers with Hf 0.5 Zr 0.5 O 2 ferroelectric has been demonstrated previously . Deposition of ZnMgO thin films on ZnO interfacial layers on Si(111) was achieved through a spin-coating sol–gel process.…”