Ge‐rich GeSbTe chalcogenide alloys have gained significant attention in the field of phase‐change materials due to their remarkable thermal stability and thus their suitability for integration in non‐volatile memories targeting embedded automotive applications. In this study we focus on the effects of different encapsulating materials on the evolution and on the crystallization kinetic of N‐doped Ge‐rich GeSbTe films. These films are annealed with temperatures compatible with the Back‐End‐of‐Line (BEOL) of the CMOS fabrication. First, we show how the encapsulation layer thickness should be tuned in order to protect the layer from oxidation and at the same time to avoid delamination phenomena. We compare TaN, C, TiN, SiC and SiN used as encapsulating layers. The segregation and crystallization of Ge‐rich GeSbTe alloys appear more homogeneous in the case of C, TiN and SiC. On the contrary we observe the effects of an interfacial heterogeneous nucleation in the case of TaN and SiN. It results in a different final morphology of the chalcogenide layer after annealing depending on the encapsulation, with different grain sizes and kinetic of phase separation.This article is protected by copyright. All rights reserved.