Critical Mg doping on the blue-light emission in p -type GaN thin films grown by metal-organic chemical-vapor deposition J. Vac. Sci. Technol. A 21, 134 (2003); 10.1116/1.1524148 Electrical properties and defect states in undoped high-resistivity GaN films used in high-power rectifiers Nominally undoped GaN films were grown by metalorganic chemical vapor deposition under three different conditions, namely (1) "standard" growth conditions with growth temperature of 1000 C and growth rate of 1 lm/h, (2) slightly reduced growth temperature of 975 C, and (3) standard temperature, but higher growth rate of 2.5 lm/h. The standard sample had a net donor density <10 15 cm À3 , while the two other samples were semi-insulating, with sheet resistivity $10 14 X/square and the Fermi level pinned at E c À0.8 eV for the low temperature growth and at E c À0.9 eV for the high growth rate conditions. The photoconductivity spectra of both of these latter samples show the presence of centers with optical threshold near 1.35 eV commonly attributed to C interstitials and centers with optical threshold near 2.7-2.8 eV and 3 eV often associated with C-related defects. However, no signals that could be attributed to substitutional C acceptors and C donors were detected. Current relaxation spectroscopy revealed deep traps with activation energies 0.2, 0.25, 045, and 0.8 eV. Annealing at 800 C increased the concentration of these traps. The changes in resistivity induced by annealing in the high-growth rate sample were much stronger than for the low-temperature sample. The authors also observed a strong suppression of the yellow luminescence band intensity in the "standard" sample after annealing, as opposed to a slight increase of this band intensity in the two semi-insulating samples. The role of compensation by native defects and by deep levels related to carbon in the observed changes is discussed.