We have investigated the magnetic and magnetotransport properties of Ba2FeMoO6 thin films produced by pulsed laser deposition from optimized bulk material. The films are comprised of grains of crystalline Ba2FeMoO6 with a disordered grain boundary region that lowers the net saturation magnetization of the film and prevents full magnetic alignment below a Curie temperature T C∼305 K. Magnetotransport measurements point to the Ba2FeMoO6 grains retaining the high spin polarization of a half-metal up to T C, while the grain boundaries greatly reduce the spin polarization of the intergrain electrical current due to spin-flip scattering. Our results show that a strong spin polarization of the electronic charge carriers is present even in Ba2FeMoO6 films that do not show the ideal bulk magnetic character.