Mg-Zn-Y alloys solidified under high pressure were characterized using XRD, DTA, SEM, and TEM. After solidification at atmospheric pressure, Mg-6Zn-1Y consisted of a-Mg, Mg 7 Zn 3 , and Mg 3 YZn 6 , while Mg6Zn-3Y consisted of a-Mg, Mg 3 Y 2 Zn 3 , and Mg 3 YZn 6 . After solidification at 6 GPa pressure, both alloys consisted of a-Mg, MgZn, and Mg 12 YZn. The size and the shape of the second-phase particles formed for atmospheric solidification were significantly different to those formed for solidification at 6 GPa pressure. In Mg-6Zn-1Y, the second-phase size decreased from 300 to 50 nm, and the shape changed from needle like to blocky. In Mg-6Zn-3Y, the size decreased from 100 to 50 nm and the shape changed from short rod like to small and round. After aging at 200°C for 12 h, the new MgZn phase transformed into the intermediate MgZn 2 phase. Increasing the aging time to 24 h caused the intermediate MgZn 2 phase to transform into Mg 7 Zn 3 with a size of 50 nm, while the Mg 12 YZn phase remained unchanged.