Clinkers with alite-belite-ye´elimite (ABY) are considered as eco-friendly cements. Clinkering (2 Kg) of two types of ABY clinkers was optimized: standard-ABY, with CaF 2 and ZnO as dopants (32.6 wt% alite, 30.4 wt% β-C 2 S and 15.6 wt% ye'elimite) and αABY, with CaF 2 , ZnO, B 2 O 3 , Na 2 O (14.4 wt% alite, 37.1 wt% β-C 2 S, 18.5 wt% α' H-C 2 S and 7.5 wt% ye'elimite). Zn and F were mainly incorporated in alite and ferrite as dopants determined by EDS semiquantitative analysis. The effect of dopants on the hydration of the cement mortars has been tested. Thus, standard-ABY develops 29.9 MPa compressive strengths at 1 day while αABY does 16.8 MPa, mainly due to the higher amount of alite of the former. The presence of α' H-C 2 S in αABY increases mechanical strengths at 28 days of hydration from 44.7 MPa of standard-ABY to 74.9 MPa. Table 8. Nominal elemental composition (as in Table 2), direct (from XRF and ICP) and derived (from LXRPD) elemental analyses, expressed as oxide weight percentages, of la-ABY_1F and la-αABY_1F0.6B0.3N clinkers.