Enhancing the catalytic efficiency and stability of photoenzymes using hydrogen-bonded organic framework material HOF-101

Abstract

The development of highly efficient artificial photoenzyme catalytic systems, inspired by natural photosynthesis, has attracted significant attention. In this study, we utilized the hydrogen-bonding organic framework material HOF-101 to embed...

Click Conjugation of Zwitterionic Peptide with DNA Strand: An Efficient Antifouling Strategy for Versatile Photoelectrochemical Aptasensor

“…30,31 Meanwhile, its planar molecular structure features a large πconjugated system, resulting in an excellent electron transport capability. 32,33 To further promote the photocurrent output, polydopamine (PDA) was utilized. As a biocompatible material, PDA exhibits a strong affinity for various substrate surfaces and possesses abundant active functional groups, which serve as essential connectors for biomolecules.…”

“…Among them, 1,3,6,8-tetrakis ( p -benzoic acid) pyrene, abbreviated as H 4 TBAPy, is a planar molecule featuring four symmetric carboxylic acid groups, forming an expansive π-conjugated system. Under certain conditions, H 4 TBAPy can self-assemble through hydrogen bonding and strong π–π stacking to form highly crystalline porous hydrogen-bonded organic frameworks, known as HOF-101. , HOF-101 possesses a moderate band gap of 2.3–2.4 eV, exhibiting significant visible-light absorption. , Meanwhile, its planar molecular structure features a large π-conjugated system, resulting in an excellent electron transport capability. , To further promote the photocurrent output, polydopamine (PDA) was utilized. As a biocompatible material, PDA exhibits a strong affinity for various substrate surfaces and possesses abundant active functional groups, which serve as essential connectors for biomolecules. , With its remarkable light absorption ability spanning the range of 200–800 nm, PDA acts as an efficient electron donor, significantly enhancing the photocurrent response. , Besides, PDA-modified surfaces demonstrate excellent hydrophilicity, facilitating their resistance to biofouling.…”

Protein‐Integrated Hydrogen‐Bonded Organic Frameworks: Chemistry and Biomedical Applications

“…For example, Tan et al. engineered a photo‐enzyme catalytic system by integrating lactate dehydrogenase (LDH) within HOF‐101 , with the incorporation of (4‐carboxyphenyl)porphyrin (TCPP) as a photocatalyst and [Cp*Rh(bpy)H 2 O] 2+ ( M ) as an electron mediator [28] . This integration markedly improved the NADH regeneration rate and facilitated electron transfer attributed to the modification and immobilization of TCPP and M .…”

Controlled crystallisation of porous crystals of luminescent platinum(ii) complexes by electronic tuning of ancillary ligands

“…3 For example, PMCs have been employed as adsorbents, 1,2 functional channels, 4 sensing/switchable materials, 5,6 and catalysts/nanoreactors. 7 Notably, in contrast to the poor solubility of most MOFs and COFs, PMCs can be easily dissolved and recrystallised in common solvents. Therefore, PMCs can be easily fabricated via solution processes and reused by recrystallisation.…”