The time-accurate prediction of a chaotic system is challenging because its evolution becomes unpredictable after the predictability time. This is because infinitesimal errors in a chaotic system increase exponentially, i.e., two nearby time series diverge from each other. An approach to the time-accurate prediction of chaotic solutions is by learning temporal patterns from data. Echo State Networks (ESNs), which are a class of Reservoir Computing, can accurately predict the chaotic dynamics well beyond the predictability time. Existing studies, however, also showed that small changes in the hyperparameters may markedly affect the network's performance. The overarching aim of this paper is to assess and improve the robustness of Echo State Networks for the time-accurate prediction of chaotic solutions. The goal is three-fold. First, we investigate the robustness of routinely used validation strategies. Second, we propose the Recycle Validation, and the chaotic versions of existing validation strategies, to specifically tackle the forecasting of chaotic systems. Third, we compare Bayesian optimization with the traditional Grid Search for optimal hyperparameter selection. Numerical tests are performed on two prototypical nonlinear systems that have both chaotic and quasiperiodic solutions. Both model-free and model-informed Echo State Networks are analysed. By comparing the network's robustness in learning chaotic (unpredictable) versus quasiperiodic (predictable) solutions, we highlight fundamental challenges in learning chaotic solutions.The proposed validation strategies, which are based on the dynamical systems properties of chaotic time series, are shown to outperform the state-of-the-art validation strategies. Because the strategies are principled-they are based on chaos theory such as the Lyapunov time-they can be applied to other Recurrent Neural Networks architectures with little modification. This work opens up new possibilities for the robust design and application of Echo State Networks, and Recurrent Neural Networks, to the time-accurate prediction of chaotic systems.