2014
DOI: 10.1111/cote.12094
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Environmentally friendly coloration of cotton by the UV‐induced photografting of α‐bromoacrylamido dyes

Abstract: Conventional wet dyeing based on dye diffusion and adsorption in water requires large amounts of salt, time, and energy. α‐Bromoacrylamido dyes are photografted onto cotton at room temperature as an environmentally friendly coloration process. Dye‐originated radicals are produced by the photoscission of the carbon–sulfur and carbon–bromine bonds of the dyes and subsequently abstract hydrogen atoms to generate cellulose radicals which can initiate graft copolymerisation. About 88% of the dyes are polymerised, a… Show more

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Cited by 11 publications
(3 citation statements)
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“…The reaction propagates by radical formation and then leads to the covalent bonding of the dye to the fabric surface. This technique has many advantages: (i) many functional monomers can be grafted to the substrate, (ii) the reaction is fast and controllable, (iii) it occurs at room temperature and thus can be applied to thermo-sensitive substrates, and (iv) more importantly it guarantees long grafting durability (Dong and Jang, 2014).…”
Section: Introductionmentioning
confidence: 99%
“…The reaction propagates by radical formation and then leads to the covalent bonding of the dye to the fabric surface. This technique has many advantages: (i) many functional monomers can be grafted to the substrate, (ii) the reaction is fast and controllable, (iii) it occurs at room temperature and thus can be applied to thermo-sensitive substrates, and (iv) more importantly it guarantees long grafting durability (Dong and Jang, 2014).…”
Section: Introductionmentioning
confidence: 99%
“…Supercritical fluid carbon dioxide (scCO 2 ) facilitates the transference of colourants by liquid/vapour transformation. Above the triple point, an increase in temperature drives state transformation .…”
Section: Introductionmentioning
confidence: 99%
“…On the other hand, Dong and Jang [18] proposed the direct photografting of wool-reactive dyes themselves onto cotton fabric. This coloration utilizes the photoreactivity of certain dyes under UV irradiation, through photopolymerization, photografting, and photocross-linking processes, to form a polymerized and cross-linked dye network.…”
Section: Introductionmentioning
confidence: 99%