Thin films of nominally pure and
10 mol % Gd-doped ceria were grown
on Al2O3⟨11̅02⟩ (r-cut)
and MgO⟨100⟩ substrates with pulsed laser deposition
(PLD). Their electrical conductivity properties were measured using
impedance spectroscopy. Oxygen partial pressure and temperature dependence
indicate that the nominally pure films are contaminated with acceptor
impurities whose concentration is found to vary perceptibly among
the samples. Quite remarkably, the nanocrystalline 10 mol % Gd-doped
thin films show conductivities that are, as expected, lower than those
for epitaxial films but surprisingly much larger than those obtained
previously from other comparable nanocrystalline films (e.g., grown
on SiO2), indicating that the oxygen vacancies are much
less depleted at the grain boundaries. Correspondingly, the space
charge potential was found to be unusually small with a value of 0.19
± 0.05 V.