Epoxy-Tethered Diels–Alder Reaction toward the Tricyclic Core of Kalihinols

Chaitanya, Nandikolla Krishna; Dinda, Shrabani; Mainkar, Prathama S.; Chandrasekhar, Srivari

doi:10.1021/acs.orglett.0c00998

Cited by 4 publications

(2 citation statements)

References 49 publications

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“…[ 10 ] Recently, a study displayed the reaction of an octadienol with 6‐me‐thyl‐5‐hepten‐2‐one to form an epoxide derivative. [ 11 ] All these reports show the synthesis of various epoxide analogues using some methods; however, some of these protocols require different conditions, among which are changes in temperature and pH. Analyzing these data, the objective of this research was to prepare two epoxy derivatives using some chemical reactions that do not require special conditions.…”

Section: Introductionmentioning

confidence: 99%

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Retracted: Design and synthesis of two epoxide derivatives from 3‐ethynylaniline

Figueroa‐Valverde

Francisco

María

et al. 2021

Journal of Heterocyclic Chem

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For several years ago, several epoxide derivatives have been prepared using different methods; however, some protocols use reagents which could be expensive and require specials conditions. The aim of this investigation was to prepare two new epoxide‐derivatives from 3‐ethynylaniline using some reactions such as oximation, acetylation, 2 + 2 addition, functionalized chloroamides, and epoxidation via Darzens reaction. The chemical characteristics of epoxide derivatives were determinate through a spectroscopic and spectrometric analysis. In conclusion, it is noteworthy that the reactions used in this study do not involve expensive reagents or special conditions for the synthesis of epoxide derivatives.

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Section: Introductionmentioning

confidence: 99%

“…Reaction mechanism of a pyridine derivative (8) I G U R E 7 Preparation of chloroamide derivatives(10)(11)(12)(13)…”

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confidence: 99%