“…Recently, there were the extensive interests in the ECAE research, and many successful applications have been reported for various metal and alloy materials with ultrafine grains, such as TiNi alloys [10][11][12][13][14][15][16][17], TiAl and TiNb alloys [18,19],Ti [20][21][22], Mg and Cu alloys [23,24] etc. Among these ultrafine grain materials, Ni-rich TiNi alloys have many applications in engineering and medical fields for their superior properties, such as the shape memory effect (SME) and the pseudoelasticity (PE) [11,25].…”