This paper is devoted to sufficient condition for Strong Metric sub‐Regularity (SMsR for short) of the set‐valued mapping corresponding to the local description of Pontryagin maximum principle for the Mayer‐type optimal control problems with convexity condition of the Hamiltonian and functional. In particular, stability property of optimal control for the Mayer‐type problem has been established for the occasion of a polyhedral control set and entirely bang‐bang solution structure. Moreover, based on the sufficiency of SMsR and stability property of optimal control, we give the approximate errors of Euler discretization methods utilized to such problems.