This paper introduces a new type of distillation column structure
that is externally heat-integrated in multiple diabatic distillation
columns (EHImxDC). By matching the temperatures of different
column sections (from the same distillation column or different distillation
columns), heat integration of different distillation column sections
is carried out to improve the thermodynamic reversibility of the distillation
operation. First, the structure of the column shell is proposed, which
may exist in this kind of distillation column. Second, the mathematical
model describing EHImxDC is established, and a concise
method is proposed to construct the EHImxDC structure.
At last, based on two conventional distillation columns for the separation
of a hexane–heptane system and a hexane–octanane system,
the heat integration in two diabatic distillation columns (EHImtDC) is established. Through simulation, the results show that
the reversibility of EHImtDC is significantly higher than
that of the conventional distillation column. By comparing the annual
operating costs of the EHImtDC and the double-effect distillation
process, it is found that the EHImtDC saved about 10% of
the annual operating cost compared to the double-effect distillation
process. It can be seen that EHImxDC can greatly improve
the second law energy efficiency of the distillation column and reduce
the energy consumption of the distillation operation.