The
use of water-soluble polymers as natural gas hydrate inhibitors
has gained interest in recent years. Variety of polymers have been
studied for their kinetic performance in methane hydrate inhibition
in the past; however, thermodynamic hydrate inhibition by water-soluble
polymers is not fully understood and needs further investigation.
This study investigates the effect of molecular weights and concentrations
of aqueous solutions of various oilfield water soluble polymers on
phase equilibrium of methane hydrate. Water-soluble polymers, such
as polyacrylamide (PAM), xanthan gum (XG), and guar gum (GG) with
two different molecular weights and varying concentrations, have been
considered for the investigations. These are as follows: PAM (Mw:
1.1 × 106 g/mol, PAM-1 and 1.5 × 105 g/mol, PAM-2), XG (Mw: 6.4 × 105 g/mol, XG-1 and
2.4 × 105 g/mol, XG-2), and GG (Mw: 1.7 × 106 g/mol, GG-1 and 6 × 105 g/mol, GG-2), with
varying concentrations of 100, 200, and 500 ppm each. These are referred
to as high-molecular-weight polymers (PAM-1, XG-1, and GG-1) and relatively
low-molecular-weight polymers (PAM-2, XG-2, and GG-2). The experiments
have been conducted in the pressure and temperature range of 8.63–5.50
MPa and 284.6–279.8 K, respectively. The results indicate that
the water-soluble polymers have shown thermodynamic hydrate inhibition
with an average temperature depression ranging from 0.25 to 1.05 K.
The molecular weight and the concentration of polymers have been shown
to affect the hydrate inhibition tendency. We have also proposed a
hypothesis for hydrate inhibition based on the mobility of the polymer
chain in the solution with a desired functional group in relation
to nonelectrolyte/electrolyte thermodynamic hydrate inhibitors. The
presented study on methane hydrate phase stability in the presence
of various oilfield polymers is vital for their use in the design
and development of hydrate inhibitive drilling fluids for offshore
wells, hydrate-bearing formations, and studies related to the recovery
of methane from hydrate-bearing sediments using polymer injection.