This paper reports that the heat transfer mechanism of phase change in a capillary tube belongs to liquid film conduction and surface evaporation. The surface evaporation is influenced by vapor temperature, vapor-liquid interfacial temperature, and vapor-liquid pressure difference. In the vapor-liquid flow mechanism, flow is effected by both the gradient of disjoining pressure, and the gradient of capillary pressure. The mechanism of vapor-liquid interaction consists of the shear stress caused by momentum transfer owing to evaporation, and frictional shear stress due to the velocity difference between vapor and liquid. In the model presented for a capillary tube, the heat transfer, vapor-liquid flow, and their interaction are more comprehensively considered. The thin film profile and heat transfer characteristics have close relations with a capillary radius and heat transfer power. The results of calculation indicate that the length of the evaporating interfacial region decreases to some extent with decreasing capillary radius and increasing heat transfer power.