1990
DOI: 10.1021/ja00174a022
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Evidence for a metastable trans-cycloalkene intermediate in the photochemistry of 1,1,4,4-tetramethyl-1,4-disilacyclohept-2-ene

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Cited by 18 publications
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“…One class comprises the transformations unstrained alkenes undergo, such as reactions with acids, [3][4][5] dihydroxylations, 5,6 and epoxidations. 7 The second class includes pericyclic reactions, [8][9][10] particularly cycloadditions with 1,3-dipoles or dienes, 1,3,[11][12][13][14][15][16][17][18][19][20][21] that often require strain to make them possible. Although strain-promoted cycloadditions have emerged as important transformations in synthesis 22 and chemical biology, 23 the scope of the reactivity of trans-cycloalkenes beyond these two classes remains limited.…”
mentioning
confidence: 99%
“…One class comprises the transformations unstrained alkenes undergo, such as reactions with acids, [3][4][5] dihydroxylations, 5,6 and epoxidations. 7 The second class includes pericyclic reactions, [8][9][10] particularly cycloadditions with 1,3-dipoles or dienes, 1,3,[11][12][13][14][15][16][17][18][19][20][21] that often require strain to make them possible. Although strain-promoted cycloadditions have emerged as important transformations in synthesis 22 and chemical biology, 23 the scope of the reactivity of trans-cycloalkenes beyond these two classes remains limited.…”
mentioning
confidence: 99%