. (2016) 'Late-stage volatile saturation as a potential trigger for explosive volcanic eruptions.', Nature geoscience., 9 (3). pp. 249-254. Further information on publisher's website:http://dx.doi.org/10.1038/NGEO2639Publisher's copyright statement:Additional information:
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Volatile variations in apatite and hydrous glassesThe volatile composition of apatite relates to that of its host liquid by a set of exchange reactions between F, Cl and OH, for example:where exchange coefficients, K, are constant at a given pressure (P) and temperature (T) (ref. 12), f is fugacity, X is mole fraction and superscripts l and Ap denote the liquid and apatite phases, respectively. We measured F, Cl and OH directly using secondary ion mass spectrometry and electron microprobe analysis (see Supplementary Methods). We neglect 4 sulphur, because S diffusion in apatite is inhibited by a coupled substitution 19 , and equilibrium is not maintained on short timescales. Apatite compositions from Astroni 1 show a negative correlation between X F and X OH and a weaker negative correlation between X Cl and X OH (where X F , X Cl and X OH are the mole fractions of F, Cl and OH, respectively;Supplementary Table 1), demonstrating this exchange of components within the crystal volatile site. Some crystals are slightly non-stoichiometric, within the range reported in other studies 20 . We focus on mole fraction ratios as these relate to liquid composition, pressure and temperature through relationships such as equation (1). Data show a positive correlation between X Cl /X OH and X F /X OH ( Fig. 2a), with one low-X Cl , high-X F outlier. In general, X F /X Cl is constant within error, except in the outlier which has high X F /X Cl ( Fig. 2b). Clinopyroxenehosted apatite inclusions extend to higher X halogen /X OH ratios than biotite-hosted apatite inclusions. Both clinopyroxene-and biotite-hosted inclusions extend to higher X halogen /X OH ratios than apatite microphenocrysts that were in contact with melt until eruption. The overall X halogen /X OH trend is apparently linear, suggesting that there was no significant relative change in F or Cl compatibility during apatite crystallization. (Fig. 3a-c). However, matrix glasses have low H 2 O contents relative to both clinopyroxene-and biotite-hosted melt inclusions, typically <1 wt% (Fig. 3d).
Modelling fractionation and volatile saturationWe model magma evolution in the Campi Flegrei system using the Rhyolite-MELTS thermodynamic software 23,24, 25,26 Disc...