1997
DOI: 10.1021/la960954w
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Examination of Ellipsoidal Polystyrene Particles by Electrophoresis

Abstract: Starting with monodisperse spherical polystyrene particles ranging in diameter from 208 nm to 3.90 μm, a series of ellipsoidal particles have been prepared by a previously published stretching technique. Both spherical and ellipsoidal particles were examined by microelectrophoresis. The electrophoretic mobilities so obtained were converted into ζ-potential values using the Smoluchowski equation and an equation obtained by O'Brien and Ward from an analysis of the electrophoretic motion of spheroidal particles.

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Cited by 40 publications
(39 citation statements)
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“…A novel or improved technique [453][454][455] inheriting abilities of microfluidics but overcoming its problems such as tedious device preparation and scalability would be another renaissance for particle production. Finally, unique mechanical, packing and assembly properties of nonspherical particles are already drawing attention [6,85,161,[453][454][456][457][458][459][460][461][462][463][464][465][466][467][468] but the effect of porosity on such regular nonspherical particles is still waiting to be further exploited.…”
Section: Discussionmentioning
confidence: 99%
“…A novel or improved technique [453][454][455] inheriting abilities of microfluidics but overcoming its problems such as tedious device preparation and scalability would be another renaissance for particle production. Finally, unique mechanical, packing and assembly properties of nonspherical particles are already drawing attention [6,85,161,[453][454][456][457][458][459][460][461][462][463][464][465][466][467][468] but the effect of porosity on such regular nonspherical particles is still waiting to be further exploited.…”
Section: Discussionmentioning
confidence: 99%
“…O'Brien and Ward [28] derived an analytical expression for the electrophoretic translation of spheroidal particles as the zeta potential increases. Ho et al [29] used this model to determine the zeta potential of ellipsoidal polystyrene particles with aspect ratios (diameter/length), between 1.0 and 4.5. Their observations deviated less than 10% from values obtained using Eq.…”
Section: Introductionmentioning
confidence: 99%
“…Heteromorphic microparticles compose a unique crystal structure for their optical properties to be investigated as new photonic crystals [19][20][21][22]. Some of them show electrophoresis [23]. The type of such functions and the magnitude of the response depend on the shape of the heteromorphic particle and its material distribution.…”
Section: Introductionmentioning
confidence: 99%