Excellent rate capabilities of (LiFePO4/C)//LiV3O8 in an optimized aqueous solution electrolyte

Zhao, Mingshu; Bao, Zhenan; Huang, Guanliang; Zhang, Hanyuan; Song, Xiaoping

doi:10.1016/j.jpowsour.2013.01.026

Cited by 72 publications

(43 citation statements)

References 36 publications

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“…Some researchers focus on studying the potential anode materials such as vanadium oxides including VO 2 [6], TiO 2 [7], LiV 3 O 8 [8], NASICON-type LiTi 2 (PO 4 ) 3 [9] and pyrophosphate compounds TiP 2 O 7 [10]. [14] and so on [15,16], the cycling performance of the batteries still needs to be improved substantially.…”

Section: Introductionmentioning

confidence: 99%

The electrochemical performance improvement of LiMn2O4/Zn based on zinc foil as the current collector and thiourea as an electrolyte additive

et al. 2015

Journal of Power Sources

117

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Section: Introductionmentioning

confidence: 99%

The electrochemical performance improvement of LiMn2O4/Zn based on zinc foil as the current collector and thiourea as an electrolyte additive

et al. 2015

Journal of Power Sources

117

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“…However, there is an optimum concentration value for the MnSO 4 additives, insufficient or excess MnSO 4 added will not lead to an improvement or worsen the electrochemical performances instead. [38,[42][43][44] Electrochemical impedance spectroscopy (EIS) measurements have been performed to investigate the electrode kinetics. As shown in Figure S6, a Nyquist plot obtained for Zn// O dc À MnO 2 revealed a linear curve in the low-frequency range with a greater gradient and a smaller semicircle in the highfrequency range as compared to the Zn//BirÀ MnO 2 .…”

Section: Resultsmentioning

confidence: 99%

Oxygen‐Deficient Birnessite‐MnO₂ for High‐Performing Rechargeable Aqueous Zinc‐Ion Batteries

et al. 2020

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The development and commercialisation of Zinc‐Ion Batteries (ZIBs) faces a daunting challenge caused by the limited selection of cathode materials. Among all the available choices, Manganese‐Based Oxides show the most promising potential due to the various benefits such as, low costs, natural abundance of Manganese, environmental benignity and its multiple valence states. Most notably, Manganese Dioxide (MnO2) as a cathode material for ZIBs has always been a popular area of research as it can exist in various phases with tunnelled and layered structures for the (de‐)intercalation of Zn2+ ions. However, despite many works reported on enhancing the electrochemical performances of MnO2, most of the proposed methodologies of improving the performance is based on Zn2+ ion insertion kinetics and these methods has been pushed to saturation. Herein, we propose an alternative direction of creating oxygen deficiency via defect engineering to enhance the surface‐capacitive electrochemical performance of MnO2. In this work, the Zn//Oxygen‐deficient Birnessite‐MnO2 achieved a specific capacity of 378 mAh g−1 which is one of the highest among other existing Zn//Birnessite‐MnO2 battery systems. Thus, this work is expected to shine light on the potential of defect engineering as a strategy to enhance electrochemical performances of MnO2.

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“…Currently, in ARLBs, the study of cathodes, such as LiCoO 2 , LiMn 2 O 4, and LiFePO 4 , is relatively mature . In aqueous solutions, these cathode electrodes have excellent electrochemical performance .…”

Section: Introductionmentioning

confidence: 99%

Excellent Rate Performance and Cycling Stability of TiP₂O₇@C/Carbon Nanotubes for the Aqueous Rechargeable Lithium‐Ion Battery

Zhao

Duan

et al. 2019

Energy Tech

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A novel anode composite, carbon‐coated TiP2O7 nanoparticles (TPO@C) decorated with carbon nanotubes (CNTs), is fabricated through a simple sol–gel method and a calcination process for aqueous rechargeable lithium‐ion batteries (ARLBs). The complete interfacial contact of TPO@C and CNTs provides a 3D network structure with a high specific surface area. The effects of CNTs on the diffusion coefficient of lithium ions, rate performance, and cycle performance are investigated. Typically, the discharge capacities of the TPO@C/CNTs anode can reach up to 97.88, 93.86, 90.79, 86.54, and 77.42 mA h g−1 at the current densities of 0.2, 0.5, 1, 2, and 5 A g−1, respectively. At an extremely high current density of 10 A g−1, the discharge capacity over 800 cycles is almost as high as the initial discharge capacity. Moreover, a (TPO@C/CNTs)//LiMn2O4 full cell in saturated LiNO3 electrolyte is tested in a pouch cell. It also demonstrates a high reversible capacity of 83.51 mA h g−1 (≈60.42% capacity retention) after 1000 cycles at 2 A g−1. The results indicate that CNTs can promote the diffusion coefficient of lithium ions, and are responsible for the high rate performance and cycling stability.

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Excellent rate capabilities of (LiFePO4/C)//LiV3O8 in an optimized aqueous solution electrolyte

Cited by 72 publications

References 36 publications

The electrochemical performance improvement of LiMn2O4/Zn based on zinc foil as the current collector and thiourea as an electrolyte additive

The electrochemical performance improvement of LiMn2O4/Zn based on zinc foil as the current collector and thiourea as an electrolyte additive

Oxygen‐Deficient Birnessite‐MnO₂ for High‐Performing Rechargeable Aqueous Zinc‐Ion Batteries

Excellent Rate Performance and Cycling Stability of TiP₂O₇@C/Carbon Nanotubes for the Aqueous Rechargeable Lithium‐Ion Battery

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Excellent rate capabilities of (LiFePO4/C)//LiV3O8 in an optimized aqueous solution electrolyte

Cited by 72 publications

References 36 publications

The electrochemical performance improvement of LiMn2O4/Zn based on zinc foil as the current collector and thiourea as an electrolyte additive

The electrochemical performance improvement of LiMn2O4/Zn based on zinc foil as the current collector and thiourea as an electrolyte additive

Oxygen‐Deficient Birnessite‐MnO2 for High‐Performing Rechargeable Aqueous Zinc‐Ion Batteries

Excellent Rate Performance and Cycling Stability of TiP2O7@C/Carbon Nanotubes for the Aqueous Rechargeable Lithium‐Ion Battery

Contact Info

Product

Resources

About

Oxygen‐Deficient Birnessite‐MnO₂ for High‐Performing Rechargeable Aqueous Zinc‐Ion Batteries

Excellent Rate Performance and Cycling Stability of TiP₂O₇@C/Carbon Nanotubes for the Aqueous Rechargeable Lithium‐Ion Battery