Densities and viscosities were determined over the whole composition range for the binary mixtures of exo-tetrahydrodicyclopentadiene with n-nonane, n-dodecane, or n-tridecane at different temperatures (293.15, 298.15, 303.15, and 313.15) K and atmospheric pressure. The excess molar volumes V
m
E for the mixtures were calculated from the experimental data. The refractive index and surface tension of the systems were also measured for temperatures of (293.15 and 303.15) K.