Excess volumes of (pyridine+an n-alkanol) and (α-picoline+an n-alkanol)

Singh, Paramjit; Sharma, B.R.; CHOPRA, P. C.

doi:10.1016/s0021-9614(80)80014-0

Cited by 5 publications

(3 citation statements)

References 7 publications

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“…The data of Findlay and Copp [25] present good agreement for ethanol + pyridine over the entire composition range. However, the results of Singh et al [36] are lower in the middle fraction region, probably because of the higher measurement temperature. From Figure 2 it can be seen that for ethanol + benzene the G* E of this work agrees well with those reported by Kouris and Panayiotou [37] over the whole composition range.…”

Section: Resultsmentioning

confidence: 78%

Thermodynamic Properties of Ethanol + Pyridine, Ethanol + Benzene, and Pyridine + Benzene Mixtures at Temperature 298.15 K and Under Atmospheric Pressure

Zeqiraj¹,

Gjevori

LLOZANA

et al. 2023

International Journal of Thermodynamics

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Experimental densities, viscosities, refractive indices, and sound speeds at temperature 298.15 K and atmospheric pressure are reported for the binary liquid mixtures of ethanol + benzene, ethanol + pyridine, and benzene + pyridine. From these experimental data, various thermodynamic excess and deviation properties were calculated and fitted by the Redlich-Kister polynomial to determine the adjustable coefficients and the standard deviations. The number of Redlich-Kister coefficients for significantly representing each thermodynamic property was optimized by applying the F-test. The variation of thermodynamic excess and deviation properties with composition has been interpreted in terms of molecular interactions between components of the mixture and structural effects. Furthermore, several theoretical and semi-empirical models were used to predict the refractive indices and sound speeds of the investigated mixtures. The predicting ability of each model was ascertained in terms of mean absolute percentage deviation between experimental and calculated data.

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Section: Resultsmentioning

confidence: 78%

Thermodynamic Properties of Ethanol + Pyridine, Ethanol + Benzene, and Pyridine + Benzene Mixtures at Temperature 298.15 K and Under Atmospheric Pressure

Zeqiraj¹,

Gjevori

LLOZANA

et al. 2023

International Journal of Thermodynamics

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“…In the discussion, the ideal liquid viscosity is defined as η ideal , which is the mole fraction average of the pure component viscosities at constant temperature and pressure. Table S1 (Supporting Information) provides a detailed list of the molecular systems and data sources ,,− and contains systems that exhibit viscosity maxima (+S), viscosity minima (−S) or positive (+), negative (−), or positive and negative (+−) deviations in mixture viscosity compared with η ideal . Parameter values shown in Table S1 for the PS viscosity model are discussed later.…”

Section: Resultsmentioning

confidence: 99%

Application of the Preferential Solvation Viscosity Model to Binary Liquid Mixtures: Aqueous, Nonaqueous, Ionic Liquid, and Deep Eutectic Solvent Systems

Duereh

Satō

Smith

et al. 2019

Ind. Eng. Chem. Res.

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The preferential solvation (PS) viscosity model was used to correlate binary liquid viscosities of aqueous, nonaqueous, nonpolar–polar, molecular solvent–ionic liquid (IL), and molecular solvent–deep eutectic solvent mixtures for the purpose of determining local composition in the chemical systems and analysis of chemical phenomena. Lignin solubility in aqueous systems was directly proportional to the population of (1–2) complex molecules. Cellulose solubility in molecular solvent–IL mixtures was directly proportional to the population of (2–2) associated molecules. Local compositions determined from the PS viscosity model were able to be used to estimate mixture solvent polarity and the variation of carbazole selectivity in crude anthracene separations. The PS viscosity model applied to chromatography allowed estimation of appropriate bulk composition regions for separations. Local compositions determined from the PS viscosity model can be used to analyze a wide variety of chemical phenomena in liquid solvent mixtures.

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“…A series of experimental work on viscosities and partly on excess volumes of mixtures of alcohols with hydrocarbons and alcohols with pyridine exists already in the literature (e.g., Canosa et al (1998), Sastry and Valand (1998), Pal and Kumar (1998), Dewan et al (1991), Singh et al (1980), Kowalski and Orszagh (1975), Nakanishi and Shirai (1970)).…”

Section: Introductionmentioning

confidence: 99%

Excess Molar Volumes and Viscosities of Binary Mixtures of 4-Methylpyridine with Methanol, Ethanol, Propan-1-ol, Propan-2-ol, Butan-2-ol, and 2-Methylpropan-2-ol at 298.15 K and Atmospheric Pressure

et al. 1999

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New experimental data on densities and viscosities for the systems 4-methylpyridine + methanol, + ethanol, + propan-1-ol, + propan-2-ol, + butan-2-ol, and + 2-methylpropan-2-ol are presented at 298.15 K and ambient pressure using a vibrating tube densimeter and an Ubbelohde viscometer. The results are discussed qualitatively in terms of the association of the mixture components caused by chainlike self-association of the alcohol molecules and cross-association between alcohol and 4-methylpyridine.

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Excess volumes of (pyridine+an n-alkanol) and (α-picoline+an n-alkanol)

Cited by 5 publications

References 7 publications

Thermodynamic Properties of Ethanol + Pyridine, Ethanol + Benzene, and Pyridine + Benzene Mixtures at Temperature 298.15 K and Under Atmospheric Pressure

Thermodynamic Properties of Ethanol + Pyridine, Ethanol + Benzene, and Pyridine + Benzene Mixtures at Temperature 298.15 K and Under Atmospheric Pressure

Application of the Preferential Solvation Viscosity Model to Binary Liquid Mixtures: Aqueous, Nonaqueous, Ionic Liquid, and Deep Eutectic Solvent Systems

Excess Molar Volumes and Viscosities of Binary Mixtures of 4-Methylpyridine with Methanol, Ethanol, Propan-1-ol, Propan-2-ol, Butan-2-ol, and 2-Methylpropan-2-ol at 298.15 K and Atmospheric Pressure

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