Exchange reactions of poly‐2‐(N‐phthalimido)ethyl acrylate with hydroxy and amino compounds

Abstract

2-(N-Phthalimido)ethyl acrylate was prepared by the reaction of N-(2-hydroxyethyl)phthalimide with acrylic acid in the presence of N,N-dicyclohexylcarbodiimide. The exchange reactions of the resulting polymer with hydroxy and amino compounds have been studied.

Synthesis, exchange reactions, and biological activity of poly(8‐methacryloxyquinoline)

“…MAQ was prepared through the reaction of 8‐hydroxyquinoline with methacryloyl chloride or through the reaction of 8‐hydroxyquinoline with methacrylic acid in the presence of N,N ‐dicyclohexylcarbodiimide (DCCI) as a condensing agent according to our previous work 13–16…”

“…MAQ was prepared through the reaction of 8hydroxyquinoline with methacryloyl chloride or through the reaction of 8-hydroxyquinoline with methacrylic acid in the presence of N,N-dicyclohexylcarbodiimide (DCCI) as a condensing agent according to our previous work. [13][14][15][16] Acid chloride method. Methacryloyl chloride was prepared by the previously reported method 21 and was used for further reactions.…”

“…Several activated esters and amides of acrylic acid, methacrylic acid, and their polymers have been described 4–9. In our previous work, we described the synthesis, polymerization, copolymerization, and exchange reactions of acrylic and methacrylic esters 10–16. Quinoline derivatives are important constituents of several pharmacologically active synthetic compounds 17–20.…”

“…[4][5][6][7][8][9] In our previous work, we described the synthesis, polymerization, copolymerization, and exchange reactions of acrylic and methacrylic esters. [10][11][12][13][14][15][16] Quinoline derivatives are important constituents of several pharmacologically active synthetic compounds. [17][18][19][20] This article reports the synthesis and polymerization of 8-methacryloxyquinoline (MAQ or III) as well as the exchange reactions of the resulting polymer with aminated and hydroxylated model compounds.…”