We report the discovery of a codimension-two phenomenon in the phase diagram of a second-order selfsustained nonlinear oscillator subject to a constant external periodic forcing, around which three regimes associated with the synchronization phenomenon exist, namely phase-locking, frequency-locking without phase-locking, and frequency-unlocking states. The triple point of synchronization arises when a saddle-node homoclinic cycle collides with the zero-amplitude state of the forced oscillator. A line on the phase diagram where limit-cycle solutions contain a phase singularity departs from the triple point, giving rise to a codimensionone transition between the regimes of frequency unlocking and frequency locking without phase locking. At the parameter values where the critical transition occurs, the forced oscillator exhibits a separatrix with a π phase jump, i.e., a particular trajectory in phase space that separates two distinct behaviors of the phase dynamics. Close to the triple point, noise induces excitable pulses where the two variants of type-I excitability, i.e., pulses with and without 2π phase slips, appear stochastically. The impacts of weak noise and some other dynamical aspects associated with the transition induced by the singular phenomenon are also discussed.