2020
DOI: 10.1080/00986445.2020.1802257
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Experimental and theoretical studies of five imidazolium-based ionic liquids as corrosion inhibitors for mild steel in H2S and HCl solutions

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Cited by 26 publications
(14 citation statements)
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“…As for the VP monomer, it exhibits a distribution of the molecular orbitals and charge similar to that of VAA [ 74 ]. On the other hand, VBIB displays the HOMO and LUMO orbitals through the imidazolium ring as reported by Cui et al [ 75 ], whereas the positive charge was localized in N and C=C of the imidazolium ring and the negative charge in the bromide anion. These results confirm that Br and C=C and the heteroatoms N and O work as reactive sites in the different polymeric blocks that favor the adsorption process through them.…”
Section: Resultssupporting
confidence: 61%
“…As for the VP monomer, it exhibits a distribution of the molecular orbitals and charge similar to that of VAA [ 74 ]. On the other hand, VBIB displays the HOMO and LUMO orbitals through the imidazolium ring as reported by Cui et al [ 75 ], whereas the positive charge was localized in N and C=C of the imidazolium ring and the negative charge in the bromide anion. These results confirm that Br and C=C and the heteroatoms N and O work as reactive sites in the different polymeric blocks that favor the adsorption process through them.…”
Section: Resultssupporting
confidence: 61%
“…The corrosion inhibitor is either an anodic or cathodic type when the maximum shift in E corr exceeds 85 mV; the inhibitor is a mixed-type inhibitor when the change in the corrosion potential is <85 mV. 15,39 The maximum shift in E corr for 1b is <85 mV, indicating the mixed-type inhibitor behaviour of 1b. Moreover, the inhibitor concentrations of 1b considerably affect β a and β c (Table 1).…”
Section: Potentiodynamic Polarisation Measurementsmentioning
confidence: 99%
“…This suggested that the inhibitor could inhibit both the cathodic and anodic reactions, and hence 1b could be considered a mixed-type corrosion inhibitor. 15 Fig. 1…”
Section: Potentiodynamic Polarisation Measurementsmentioning
confidence: 99%
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“…It is highly electropositive and has a high resistance to corrosion due to the presence of a thin oxide film. [ 14,15 ] Polyphenol flavonoids as an extract of onion skin has been introduced extensively as an efficient green inhibitor on metals; boiled red onion skin extract has a high coating efficacy against corrosion of tin in acidic solution. [ 16 ] It also reached maximum coating efficacy on carbon steel.…”
Section: Introductionmentioning
confidence: 99%