Laminates made of metal—glass fiber-reinforced polymers—metal layers require material parameters for each constitutive model of the constituents. First, although parameter identification for metallic materials has been frequently discussed, the stepwise identification of material parameters in terms of uncertainties of previously determined parameters is investigated by the concept of error propagation. Second, the calibration of a model of orthotropy describing the large deformation behavior of the glass fiber-reinforced kernel layer is a challenging process, especially against the background of a reliable determination of the parameters. The main problem is related to the lack of available experiments. This issue is embedded in the concept of local identifiability. Thus, the article provides experiments to determine the parameters of both the steel as well as the glass fiber-reinforced polymers. Particularly for the latter issue, $$\mu $$
μ
-CT data is chosen to provide a representative volume element, where all deformation modes can be investigated. In this sense, a concept to determine all material parameters in a locally unique and reliable manner is studied. A linear error propagation concept provides the uncertainty of the resulting material parameters of the whole parameter set for the homogenized material. The entire parameter identification process is discussed thoroughly, and validation examples such as bending and deep drawing in metal forming processes, are provided to estimate the prediction accuracy. In this respect, the uncertainties found by parameter identification are applied to the prediction of finite element simulations of layered metal–composite–metal forming processes and error propagation is used to estimate the uncertainties of the simulations. In this contribution, we restrict ourselves to experiments at room temperature.