“…In order to unravel its mechanism, the spraying process and modes of electrospray have been visualized and characterized since the early 20th century. , With the development of improved imaging techniques, nowadays clearer images of electrospray can be captured at high resolutions and frame rates. − Besides, with the aid of image treatment techniques, electrospray images can be processed: to provide clearer images as compared with raw images, to calculate velocity map, , or even to identify spraying modes automatically by a computer program. , In addition to the above-mentioned direct observation methods, involving adoption of image sensors, various indirect approaches for investigation of charged droplet size, number of charges, droplet evaporation and discharge hydrodynamics, and ionization mechanisms have also been proposed, including: scanning electron microscopy, phase Doppler interferometry, ,− or differential mobility analysis . Indirect methods do not provide the spraying image of electrospray optically, but they do provide other valuable information that cannot be obtained using the direct methods.…”