Experimental densities and virial coefficients for steam from 348 to 498 K with correction for adsorption effects

Eubank, Philip T.; Joffrion, L. Lane; Patel, Mukund R.; Warowny, W.

doi:10.1016/0021-9614(88)90109-7

Cited by 61 publications

(55 citation statements)

References 22 publications

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“…Table 1 gives the virial coefficients from T = 273.15 K to T = 328.15 K in steps of 5 K. The second virial coefficients of pure water vapor were taken from the NBS/NRC Steam Tables of 1984. (15) These values are in excellent accord with the recent measurements of Eubank et al, (16) and with those of Noppe, (17) Bohlander et al, (18) and LeFevre et al (19) These new values have led Tsonopoulos and Heidman (20) to revise the Tsonopoulos generalized corresponding-states correlation for the second virial coefficient of water by changing the polar term accordingly. The second virial coefficients of oxygen were taken from the compilation of Dymond and Smith.…”

Section: Methodssupporting

confidence: 88%

Solubility of gases in liquids. 22. High-precision determination of Henry’s law constants of oxygen in liquid water fromT=274 K toT=328 K

Rettich

Battino

Wilhelm

2000

The Journal of Chemical Thermodynamics

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Section: Methodssupporting

confidence: 88%

Solubility of gases in liquids. 22. High-precision determination of Henry’s law constants of oxygen in liquid water fromT=274 K toT=328 K

Rettich

Battino

Wilhelm

2000

The Journal of Chemical Thermodynamics

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“…Based on the uncertainty of the measurements, the latter is preferred for fitting the new formulation. From 350 K to 500 K the data sets are consistent with except of Hendl et al [17] measurement. In the following region to 800 K the data sets are rather inconsistent and difficult to assess.…”

Section: Discussionsupporting

confidence: 85%

“…The re-evaluation will be used for developing a new analytical representation of second virial coefficient as a function of the internal energy. As the earlier step a following function was developed Developed model is compared with the re-evaluated data, previously published virial coefficients by Adulagatov et al [16], Eubank et al [17], Hendl et al [18], Kell et al [19] and [20] and with previous models: IAPWS95 [4], Hill and MacMillan [21] and Le Fevre et al [22] as can be seen from figure 6 for lower internal energy of ideal gas and from figure 7 for higher one.…”

Section: A B T B Tmentioning

confidence: 99%

Re-evaluation of experimental data on the second virial coefficient for steam and development of its analytical representation as a function of the internal energy

Duška

Hrubý

2013

EPJ Web of Conferences

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Abstract.A re-evaluation of the second virial coefficient of steam is presented in the paper. The work is a part of broader effort to develop a formulation of the properties of dry and metastable steam suitable for CFD computations. The re-evaluation follows up previous work by Harvey and Lemmon [1], however with a special care for the lower temperature region close to the triple point and including more experimental data. The second virial coefficient was evaluated from volumetric (pvT) data, calorimetric measurements for saturated vapor, steam expansion experiments (measurements of the Joule-Thomson coefficient and the isothermal throttling coefficient) and measurements of the speed of sound. To accurately evaluate the uncertainty of calorimetric measurements, the uncertainty of the temperature derivative of the saturation pressure was determined based on refitting of the IAPWS saturation pressure formula to the experimental data. In the second step, the evaluated data and their uncertainties were used to develop an analytical formula to compute the second virial coefficient as function of internal energy in a range corresponding to the ideal-gas temperatures from 273.16 K to 1073.15 K. The choice of internal energy and density as independent variables is required for the CFD computations to avoid time-consuming iterations.

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“…Table XII͒. At 373 K Eubank et al 57 obtained 451Ϯ18 cm 3 /mol, showing the increase of the experimental error bars with the decrease of temperature. For temperatures below 373 K experimental uncertainties are not available but, as mentioned above, are expected to be large.…”

Section: Second Virial Coefficientmentioning

confidence: 87%

Water pair potential of near spectroscopic accuracy. I. Analysis of potential surface and virial coefficients

Mas

Bukowski

Szalewicz

et al. 2000

The Journal of Chemical Physics

170

196

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A new ab initio pair potential for water was generated by fitting 2510 interaction energies computed by the use of symmetry-adapted perturbation theory ͑SAPT͒. The new site-site functional form, named SAPT-5s, is simple enough to be applied in molecular simulations of condensed phases and at the same time reproduces the computed points with accuracy exceeding that of the elaborate SAPT-pp functional form used earlier ͓J. Chem. Phys. 107, 4207 ͑1997͔͒. SAPT-5s has been shown to quantitatively predict the water dimer spectra, see the following paper ͑paper II͒. It also gives the second virial coefficient in excellent agreement with experiment. Features of the water dimer potential energy surface have been analyzed using SAPT-5s. Average values of powers of the intermolecular separation-obtained from the ground-state rovibrational wave function computed in the SAPT-5s potential-have been combined with measured values to obtain a new empirical estimate of the equilibrium O-O separation equal to 5.50Ϯ0.01 bohr, significantly shorter than the previously accepted value. The residual errors in the SAPT-5s potential have been estimated by comparison to recent large-scale extrapolated ab initio calculations for water dimer. This estimatetogether with the dissociation energy D 0 computed from SAPT-5s-leads to a new prediction of the limit value of D 0 equal to 1165Ϯ54 cm Ϫ1 , close to but significantly more accurate than the best empirical value.

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Experimental densities and virial coefficients for steam from 348 to 498 K with correction for adsorption effects

Cited by 61 publications

References 22 publications

Solubility of gases in liquids. 22. High-precision determination of Henry’s law constants of oxygen in liquid water fromT=274 K toT=328 K

Solubility of gases in liquids. 22. High-precision determination of Henry’s law constants of oxygen in liquid water fromT=274 K toT=328 K

Re-evaluation of experimental data on the second virial coefficient for steam and development of its analytical representation as a function of the internal energy

Water pair potential of near spectroscopic accuracy. I. Analysis of potential surface and virial coefficients

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