This review covers the solubility of oxygen and ozone in liquids as a function of temperature and pressure. Solubility data for individual systems were critically evaluated and recommended or tentative values presented in many cases. The trend of solubilities in homologous series or related solvents is discussed. Liquids include water; seawater; aqueous salt solutions; mixed solvents; hydrocarbons; organic compounds containing oxygen, halogen, sulfur, nitrogen, or silicon; olive oil; and human blood. For ozone, only its solubility in water is presented. Key words: aqueous solutions; biological fluids; gas solubility; hydrocarbons; mixed solvents; organic solvents; oxygen; ozone; seawater; water.
This review covers the solubility of nitrogen and air in liquids as a function of temperature and pressure~ Solubility data for individual systems were critically evaluated. Recommended or tentative values are presented as smoothing equations and/or in tabular form. Trends in homologous series or related solvents are discussed. Data for the n-alkanes were smoothed with respect to temperature, pressure, and carbon number. Liquids include: water; heavy water; seawater; aqueous salt solutions; mixed solvents; hydrocarbons; organic compounds containing oxygen, halogen, sulfur, nitrogen, or silicon; olive oil; various biological fluids; H 2 S; S02; NH 3 ;, CO 2 ; nitrogen oxides; and several halogen and boron containing inorganic solvents.
Precision density measurements on "gas-free" and "gas-saturated" water (at a total pressure of about 100 kPa and at 208,15 K) yield partial molar volumes at essentially Infinite dilution (Y2") of 20 fluids (about half of them supercritical) In liquid water. The experimental technique Is based on vlbratlng-tube densknetry under flow conditions, the precision of which Is In the range of a few parts per million. The results for the supercritical solutes can be correlated well with a corresponding states relation due to Brelvl and O'Connell, whereas a strictly empirical linear relation between Y2" and Ve2 (critical volume of solute) Is valid for all solutes Investigated.
The following corrections are required in the original article 1 as detailed below: 1. In Eq. (40), the second term should be positive (rather than negative) to read: ln x 1 ¼ À5:7645 þ 3:9149=t þ 0:077743ðP=MPaÞ þ 0:89104 lnðP=MPaÞ: ð40Þ 2. Table 34 should have all of the numbers in the table changed to the ones below. Please note that these new numbers have been compared with one of the original sources and that they are all of comparable value considering the smoothing. The solubilities decrease with increasing temperature and increase with increasing pressure.
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