Dielectronic recombination (DR) rate coefficients for 22 sodium-like ions, between Mg+ and Xe 43+ , forming magnesium-like ions have been calculated as part of the assembly of a level-resolved DR database necessary for modelling dynamic finite-density plasmas, within the generalized collisional-radiative framework. Calculations have been performed from both ground and metastable initial states, in both LS -and intermediate coupling, allowing for ∆n = 0 and ∆n = 1 core-excitations from ground and metastable levels. Partial and total DR coefficients have been calculated for Mg + to Zn 19+ , as well as Kr 25+ , Mo 31+ , and Xe 43+ . Results for a selection of ions from the sequence are discussed in the paper and compared with existing theoretical and experimental results. A full set of results can be accessed from the Atomic Data and Analysis Structure (ADAS) database or from the Oak Ridge Controlled Fusion Atomic Data Center (http://www-cfadc.phy.ornl.gov/data_and_codes).